For thinfilm silicon solar cells, light trapping schemes are of uppermost importance to harvest all available sunlight. Nanoimprint lithography of light trapping patterns in solgel coatings for thin film silicon solar cells maurits c. Direct patterning of oxides using thermal nanoimprint lithography is performed using either the sol gel or methacrylate route. Large area direct nanoimprinting of sio tio gel gratings. Preferred materials for nanoimprint lithography are solgelbased materials, i. Solgel chemistry is very versatile and structuring solgel materials will allow a fine tuning of chemistry, electromagnetic, optical and mechanical properties. Highresolution substrateconformal imprint lithography in silica solgel resist.
Solgel methods the solgel process may be described as. A novel imprinting procedure, new mold surface passivation, and an effective surfactant added to sol were. Bo lindholm mikkelsen, rodolphe marie, jan harris hansen, hans ole nielsen, and anders kristensen deposition of solgel sensor spots by nanoimprint lithography and hemiwicking, proc. Lastly, for large volume production the complete process is carried out by our automated lithography tool, capable of manufacturing up to 60 wafers per hour. Pdf fabrication of surfacepatterned zno thin films. Solgel, coating, materials, surface, nanotechnologies. Surfacepatterned zno thin films were fabricated by direct imprinting on zno sol and subsequent annealing process. The solgel process is a wetchemical technique used for the fabrication of both glassy and ceramic materials. This formuation enables the soft nanoimprint lithography on several substrates, including polymers by the solgel process. Lowstress hyperbranched polymersilica nanostructures.
Otherwise for a periodicity of 400 nm we have obtained a collapse effects of the pillars on pdms stamp. Patterned zno gel films were fabricated by nanoimprint of polymeric zno sols with pdms stamp. In the nil process, a prefabricated mold containing an inverse of the desired patterns is pressed onto a resistcoated substrate to replicate the patterns via mechanical. Nanoimprint lithography of light trapping patterns in solgel. Pdf large area direct nanoimprinting of sio2tio2 gel. Pdf nanoimprint planarization of high aspect ratio nanostructures. The process involves conversion of monomers into a colloidal solution that acts as the precursor for an integrated network or gel of either discrete particles or network. A cm2, respectively, in comparison to that of flat peng. Nanoimprint lithography nil foundry moxtek moxtek offers state of the art nil volume manufacturing on 8inch glass and silicon wafers. Nanoimprinting of refractiveindexmatched indium tin oxide. In most solgel systems for the synthesis of oxide materials, gelation i. To realize a largescale 1 m 2, costefficient structuring technology and thus industrial use only ultraviolet. In solgel imprint lithography, a solgel material is used as the imprint resist that transfers a pattern from an elastomer stamp to a desired substrate 2326.
Solgel resists are prepared from the methyltriethoxysilane mteos sol mixed. In both cases the conversion of the hbp is independent of composition and obeys a timeintensity superposition with powerlaw dependence on uv intensity. Nanostructured optical element by unique sol gel glass material on glass substrate. The aim of this chapter is to answer the questions.
Further, the peng demonstrates uniform output characteristics over the entire device area thanks to uniform nanoimprint pillar array. Finally, crystalline zno films were obtained by subsequent annealing of the patterned zno. Imprinting is carried out with a transparent template quartz glass or soft working stamps and the imprinted structures are cured by uvlight exposure which crosslinks the resist. This formulation is low cost, very easy to use and can be adapted to specific surface requirements. The semiconductor and hard disk drive industries are investi. Low pressure and zero damage characteristics are further enhanced through a choice of patented solgel resists, applied by capillary action. In softnanoimprint lithography, a rubber negative stamp is. Multifunctional metasurfaces based on direct nanoimprint of. This soft nanoimprint method, mainly manual, and the liftoff process with sacrificial layer under sio 2 solgel permit to product easily sensors at low cost, thereby this method is compatible with mass production. This soft nanoimprint method, mainly manual, and the liftoff process with sacrificial layer under sio 2 sol gel permit to product easily sensors at low cost, thereby this method is compatible with mass production.
The solgel method results in resists with long shelflife, but with. Deposition of solgel sensor spots by nanoimprint lithography. Consequently, the light output power in leds with the ri. Later it was revealed that it does not only apply to silica materials but also to almost all other types of metal oxides and some nonoxides.
Bragg grating structure in a solgel silica waveguide is fabricated on the basis of nanoimprint lithography for biophotonic applications. Siliconbased research has drawn much attention in recent years with targeted organizations such as the international solgel society hosting workshops, 1 and the solgel gateway 2 hosting a compendium of information regarding the solgel field including conference information. The bottomup formation of solid material, which is provided by the solgel process, enables control of the chemical composition and porosity of the material. Litt sematech 257 fuller road suite 2200 albany, new york 12203 email. This solgel layer is printed by a pdms mold, which is itself printed by a semiconductor matrix. In materials science, the solgel process is a method for producing solid materials from small molecules. Sol gel resists are prepared from the methyltriethoxysilane mteos sol mixed. A soft lithographyinspired approach to micrometerscale patterning. There is a typical sol gel transition during the thermal nanoimprint process, the polymeric precursor zno sols were curing by thermal force and organic solvents in the precursor sols were diffused into pdms polymeric stamps during this. This solgel layer is printed by a pdms mold, which is itself printed by a semi conductor matrix. Lithography nil has emerged as a promising technique for surface patterning, opening for. Gratings with 300 nm pitch and 80 nm linewidth and waveguide gratings with varying periods were imprinted in a.
We offer highly durable nanostructured optical elements on glass substrate in mass production level. However, there is only little understanding of the rheological properties responsible for their good imprint ability. In the recent years significantly more progress was made with development and commercialization of this technology. The soft nanoimprint lithography on sol gel is an easy alternative to uv lithography. Dipcoating of glass substrates and subsequent uvcuring yielded thin.
Nanoimprint is aviable, scalable, and costeffective solution for large area. Fabrication of surfacepatterned zno thin films using solgel. Lowstress hyperbranched polymersilica nanostructures produced by uv curing, solgel processing and nanoimprint lithography geiser, v. The solgel process is a versatile solution process for making advanced materials, including ceramics and organicinorganic hybrids. The bottomup formation of solid material, which is provided by the sol gel process, enables control of the chemical composition and porosity of the material. Typically, randomly textured tco front layers are used to scatter the light diffusively in pin cells on glass. Generation of meso patterns with 2d order on an inorganic solgel film surface using a stamp and a substrate, each having strictly 1d features, is the key novel aspect of the work, as it is a. Hybrid polymer solutions suitable for uv nanoimprint were synthesized by combination of an alkoxysilane binder mixture with silica nanoparticles. It is mostly used for the synthesis of metal oxides. Among the existing methods, nanoimprint lithography nil emerges as a simple route for surface patterning at the submicrometer scale over large areas. Fabricating 90 nm resolution structures in solgel silica.
Large area direct nanoimprinting of sio tio gel gratings for. Fabrication of surfacepatterned zno thin films using sol. High quality 3d photonics using nano imprint lithography. We report highperformance piezoelectric nanogenerators pengs with nanoimprinted solgel batio3 bto nanopillar array polarized under high electric field and ultraviolet. The polymerbased zno sols were deposited on various substrates for the nanoimprint lithography and converted to surfacepatterned zno gel films during the thermal curing nanoimprint process. Introduction solgel is a methodology of producing small particles in material chemistry. Nanoimprint lithographic surface patterning of sol gel fabricated nickel ferrite nife2o4 volume 3 issue 4 goran rasic, justin schwartz skip to main content accessibility help we use cookies to distinguish you from other users and to provide you with a better experience on our websites. Direct patterning of oxides using thermal nanoimprint lithography is performed using either the solgel or methacrylate route. Nanoimprint lithographic surface patterning of solgel. Periodic nanostructures imprinted on hightemperature stable. Nanoimprint lithography of light trapping patterns in sol. Franziska back, matthias bockmeyer, eveline rudigiervoigt and peer lobmann, hybrid polymer sol gel material for uv nanoimprint. Periodic nanostructures imprinted on hightemperature. Hybrid polymer solutions suitable for uvnanoimprint were synthesized by combination of an alkoxysilane binder mixture with silica nanoparticles.
Lowstress hyperbranched polymersilica nanostructures produced by uv curing, solgel processing and nanoimprint lithography vale. The process realizes nonstandardized lithography in solgel silica at a high resolution for a relatively large area in the range of several micrometers with a resolution in the order of several nanometers. Nanoimprint lithography is a versatile technique for the. High quality 3d photonics using nano imprint lithography of fast solgel materials. Sol gel nanoimprint is cuttingedge nanostructure patterning technology with unique sol gel glass material. We explore the possibilities to combine sol gel chemistry to large scale patterning at low cost and high throughput. Jan 17, 2011 in uvnil, a substrate is spin coated or drop dispensed with a uvcurable monomer or oligomer. Chemical solutions for soft nanoimprint lithography this formuation enables the soft nanoimprint lithography on several substrates, including polymers by the solgel process. Low pressure and zero damage characteristics are further enhanced through a choice of patented sol gel resists, applied by capillary action. Chou and the team in 1995 as a simpler, lowcost, and highthroughput alternative to micro and nanofabrication. Chapter two describes the scil soft nanoimprint process and introduces a novel silica solgel imprint resist.
During the solgel imprint process, a colloidal solution, i. Solgel has emerged in the late 20 th century as an alternative soft method to produce ceramic materials from inorganic molecular precursors without going through a drastic thermal treatment step. Hydrolysis and condensation reactions were monitored by nmr and viscosity measurements. Large area direct nanoimprinting of sio2 tio2 gel gratings for. Generation of meso patterns with 2d order on an inorganic sol gel film surface using a stamp and a substrate, each having strictly 1d features, is the key novel aspect of the work, as it is a. A novel imprinting procedure, new mold surface passivation, and an effective surfactant added to sol were developed. Sol gel chemistry is very versatile and structuring sol gel materials will allow a fine tuning of chemistry, electromagnetic, optical and mechanical properties.
May 05, 2008 5 may 2008 nanoimprint lithography of light trapping patterns in solgel coatings for thin film silicon solar cells. Nanocomposite materials based on a hbp and silica are produced using either a dualcure solgel and photopolymerization process or by mixing silica nanoparticles with the hbp. Soft nanoimprint lithography on sio2 solgel to elaborate. A sol is a stable dispersion of colloidal particles or polymers in a solvent. Nanoimprint lithographic surface patterning of solgel fabricated nickel ferrite nife2o4 volume 3 issue 4 goran rasic, justin schwartz skip to main content accessibility help we use cookies to distinguish you from other users and to provide you with a better experience on our websites. The planarization results are strongly dependent on parameters such as pressing pressure, hydrophobicity of feature surface, spin conditions for solgel, and. Here, we investigate methods to texture the back contact with both random and periodic textures, for use in nip cells on opaque foil. Experimental sncl4 99% and ethylene glycol reagent grade were obtained from aldrich and fisher, respectively, and used as received. Based on data from 10,000 processed wafers, we have shown stamp life well in to the 500 to 750 print ranges with some life time test up to 0 prints, and minimally maintained critical dimension cd of. Solgel materials for optofluidics process and applications. Solgel derived materials have a wide range of uses. These include nanostructured surfaces, nanoparticles, nanoporous materials, etc. Multifunctional metasurfaces based on direct nanoimprint.
Fast solgel materials 15 offer a robust and ultratransparent materials to form the final high quality devices more details on fast solgel. The pengs fabricated using this method demonstrate greatly enhanced output voltage of. Nanoimprinting of refractiveindexmatched indium tin. Preparation of nanostructured tin oxide using a solgel. In this process, the sol or solution evolves gradually towards the formation of a gellike network containing both a liquid phase and a solid phase. Nanoimprint lithography nil was introduced by prof. Scil, uvscil, nanoimprint lithography, solgel, stamp lifetime, stamp degradation. Thereby longterm stable systems were produced as a prerequisite for industrial application. The sol gel method results in resists with long shelflife, but with.
Replication of butterfly wing and natural lotus leaf. Chemical solutions for soft nanoimprint lithography solgel. The approach introduced here is simple, effective, reliable, and reproducible way to fabricate highperformance solgelbased pengs and electronic devices. Pdf substrate conformal imprint lithography for nanophotonics. Solgel nanoimprint is cuttingedge nanostructure patterning technology with unique solgel glass material. We demonstrated an economical way of fabricating gelfilmbased devices by combining nanoimprint lithography nil and a solgel technique. There is a typical solgel transition during the thermal nanoimprint process, the polymeric precursor zno sols were curing by thermal force and organic solvents in the precursor sols were diffused into pdms polymeric stamps during this.
Nanoscale spatial limitations of largearea substrate conformal. We explore the possibilities to combine solgel chemistry to large scale patterning at low cost and high throughput. Peetersb aecn solar energy, westerduinweg 3, 1755 le, petten, the netherlands. Formation of an oxide network through polycondensation reactions of a molecular precursor in a liquid. The ito solgel nanostructures annealed at 300 c have ri of 1. At early stages of gelation, thin gel coatings can be structured by nanoimprint lithography, and purely inorganic silica materials can be obtained by subsequent thermal annealing. Author manuscript, published in journal of solgel science. Arraylike surface patterned zinc zirconium oxide thin films 5163 nm thickness on soda lime silica glass substrate were prepared by solgel soft lithography from the precursor solutions 8 wt% equivalent metal oxides having zinc acetate dihydrate za and zirconium oxychloride octahydrate zoo 0100 mol% w. Highperformance piezoelectric nanogenerators via imprinted. Fabrication methods this chapter summarises some of the methods used for the fabrication of nanomaterials, meaning materials with at least one dimension in the nanoscale regime 1100nm. Franziska back, matthias bockmeyer, eveline rudigiervoigt and peer lobmann, hybrid polymer solgel material for uvnanoimprint. Uvnanoimprint lithography overview and systems available.
To realize a largescale 1 m 2, costefficient structuring technology and thus industrial use only ultravioletbased imprint technique can meet all these requirements. Dependence of precursor composition on patterning and. Nanostructuration of solgel thin films techconnect briefs. A gel consists of a porous, threedimensionally continuous solid network surrounding and supporting a continuous liquid phase wet gel. The polymerbased zno sols were deposited on various substrates for the nanoimprint lithography and converted to surfacepatterned zno. Gratings with 300 nm pitch and 80 nm linewidth and waveguide gratings with varying periods were imprinted in a single step and with.
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